He's in love with her, she's in love with him, he's mad at him for being in love with her, and she doesn't realize he loves her. Set in rural England in 1799, the hardworking well-respected carpenter Adam Bede falls in love with the dairymaid Hetty Sorrel, as the upper-class Arthur Donnithorne also falls in love with Hetty, and pursues a relationship with her in a classic tragedy of seduction and betrayal that ends with a happy ending for some but not for all.
First, this novel focuses on psychological realism. Eliot's free writing style allows us to inhabit each and every character, from Dinah, the preacher, to Hetty the dairymaid, to the old folks, the Church goers, the upper-class Donnithorne, to Seth, Adam's brother, and their parents. You get to live within the world of these rural English people. They may not be rich or have much, but they have values like church going, family, eating good home-cooked meals with the family, and hardwork. The other side of this realism is the inner mind of Hetty later with this novel, when she is charged with the crime of letting her baby die and eventually ends up being hanged.
Second, this novel has moral complexity. Hetty isn't exactly a crazed lunatic killer when she lets her baby die of exposure in the woods. She's a tragic character that didn't know where to turn. Arthur isn't exactly innocent when he finds out Hetty is pregnant and he ends the relationship and goes abroad to Ireland, only to come back to find that Hetty let the baby die after she ran away from marriage with Adam. Dinah the preacher seems to be the only true god-blessed person in the book, as she's a preacher and ends up marrying Adam at the very end. So there is some happiness.
Third, this novel has a lot of pastoral imagery of a rural England of old. From Adam working at his carpentry workshop business and working a farm, to Hetty doing chores around the house, to the Church dinner celebrating Adam Bede's success, even the scenery and backgrounds where the characters live in and interact in, is almost like additional characters in and of themselves.
In addition, this novel includes a lot of Church and Methodist preaching, a lot of it by a character named Dinah. There are many preaching chapters in the novel. Oftentimes, this can slow down the narrative of the novel and prolong the novel. You'll find that Dinah's preaching often overrides the novel itself. This display of religious preaching fervor takes over much of the novel. However, this could be because that's the world in which these characters inhabit, and because that was the world of England in 1799, ultimately making the novel much stronger in its realism.
Ultimately, though, we find that in the end this is a very rewarding experience. We find that Adam's love interest in Hetty was genuine, but that doesn't mean that other men couldn't have been interested in her and courted her. Arthur's remorse after the death of the baby and Hetty's death is lifelong, and Hetty's tragedy is a reminder to society that poor women have no safety net; if they do something wrong and have no money or help like to say, raise a baby, they might have no choice but to give the baby up or worse, a sad reminder that poor women are often the most neglected members of society within any time period throughout history.
Lastly, although written in 1859, Adam Bede reads like a modern literary novel, albeit even with all the Methodist preaching. I would also recommend reading Eliot's The Mill On The Floss, for a more biographical take also in a rural England setting. And of course, you should've already read Middlemarch, if you've read any of George Eliot's works.